Spain: tap water is safe to drink.
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Tap water is safe to drink throughout Spain, though many locals prefer bottled water for taste.
Yes — since tap water is safe in Spain, ice made from it is generally fine too.
Brushing your teeth with tap water is usually fine even where drinking it isn't recommended, but if you want to be extra cautious in Spain, use bottled water for that too.
Sealed bottled water from a reputable brand is widely available and the simplest safe option in Spain — just check the seal is intact before drinking.
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